Transition Metal Nanostructures: Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd4 Hybridization (Adv. Sci. 4/2016)
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چکیده
منابع مشابه
Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd4 Hybridization
A quasi-sd4 hybridization state for group VIIIB and IB face-centered cubic (FCC) transition metals in low-dimensional nanostructures is identified, in contrast to the sd5 hybridization state in bulk. For Au, a novel three-shelled nanowire is designed with a hexagonal close-packed core in the sd5 hybridization, wrapped by FCC-(111) shell that adopts the quasi-sd4 hybridization. This new nanostru...
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